Poly[μ2-aqua-(μ3-2,5-dichlorobenzenesulfonato)sodium]
نویسندگان
چکیده
In the title compound, [Na(C(6)H(3)Cl(2)O(3)S)(H(2)O)](n), the Na(I) ion is penta-coordinated by three dichloro-benzene-sulfonate anions and two water mol-ecules, forming a distorted trigonal-bipyramidal geometry. The Na(I) ions are bridged by the sulfonate groups and the water mol-ecules, leading to a polymeric layer structure parallel to the bc plane in which O-H⋯O hydrogen bonds are observed.
منابع مشابه
Crystal structures and hydrogen bonding in the isotypic series of hydrated alkali metal (K, Rb and Cs) complexes with 4-aminophenylarsonic acid
The structures of the alkali metal (K, Rb and Cs) complex salts with 4-amino-phenyl-arsonic acid (p-arsanilic acid) manifest an isotypic series with the general formula [M2(C6H7AsNO3)2(H2O)3], with M = K {poly[di-μ3-4-amino-phenyl-arsonato-tri-μ2-aqua-dipotassium], [K2(C6H7AsNO3)2(H2O)3], (I)}, Rb {poly[di-μ3-4-amino-phenyl-arsonato-tri-μ2-aqua-dirubidium], [Rb2(C6H7AsNO3)2(H2O)3], (II)}, and C...
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